In case of net ionic reactions, the same charge must be present on both sides of the unbalanced equation. Thus, each side of the equation must represent the same quantity of any particular element. Took me 3 minutes to set up the algebraic equations and few more minutes to solve them all.In a chemical reaction, the quantity of each element does not change. I mean, it will help in terms of keeping track on the number of atoms, but I’ll still need to do perform trial and error with the three atoms. It’s not going to be much better if I use Method 2 either. ![]() ![]() By the way, that’s EVERY single term on the right! I don’t know bout you, but I know I have better use of my time than to play trial and error with these 3 atoms. ![]() On the right, it’s in Fe 2(SO 4) 3, Cr 2(SO 4) 3, CO 2, H 2O, K 2SO 4 and KNO 3. On the left, it’s in K 2Cr 2O 7 and H 2SO 4. That’s considered the easier atom among the three. I mean look at K, on the left, it appears in K 4 and K 2Cr 2O 7, and on the right, I see it in K 2SO 4 and KNO 3. What’s 3 more atoms (K, S and O), right? WRONG!!! Those 3 that are left are tough and that’s because they appear in multiple terms all over the place. So far I have balanced Fe, C, N, H and Cr. Well, how about that? Is it my lucky day or what? There’s 2 on the left and 2 on the right. Well, look at that! It’s already balanced! Moving on to Cr. Gaining momentum and confidence… 3 down, 5 more to go. Piece of cake, kinda like C – 12 on the left and 1 on the right. That means I’ll place a “12” in front of CO 2.Ģ K 4 + K 2Cr 2O 7 + H 2SO 4 → Fe 2(SO 4) 3 + Cr 2(SO 4) 3 + 12 CO 2 + H 2O + K 2SO 4 + KNO 3 S looks tough since I see it in multiple terms on both sides. Great! I can do this….add a “2” on the left, in front of K 4, so now I have:Ģ K 4 + K 2Cr 2O 7 + H 2SO 4 → Fe 2(SO 4) 3 + Cr 2(SO 4) 3 + CO 2 + H 2O + K 2SO 4 + KNO 3.įe is balanced, for now. First question, how should I balance K? I know I’ll need to “double” the K counts on the right, but which term should I start with – K 2SO 4 or KNO 3? Not sure. Ok…what about on the right? Looks like a total 3 K on the right. I started with K since it’s the first atom I encounter from the left. How long do you think it will take to balance it? Which has 8 types of atoms in the equation: K, Fe, S, C, N, Cr, O and H. So, imagine if you have a real complex equation like this: K 4 + K 2Cr 2O 7 + H 2SO 4 → Fe 2(SO 4) 3 + Cr 2(SO 4) 3 + CO 2 + H 2O + K 2SO 4 + KNO 3 I mean, who wants to spend 30 minutes trying to balance ONE equation? Seriously, that 30 minutes is probably better-spent doing other things like watching YouTube, checking out latest posts in FB, Instagram, Twitter, uploading pictures to Snapchat, level up in that favorite game of yours or doing other things that will increase your happiness. ![]() There’s nothing wrong with that, but I think it gets a little daunting when it comes to having to keep track of multiple numbers of atoms (like 5 or more) and it will prolong the process unnecessarily. Most of the students I have worked with only knew Method 1 from their high school science/chemistry class. My quick google search seems to point towards Method 1 (by inspection or trial-error-method) and Method 2 (writing down atom counts) being the most popular methods when it comes to balancing equations. Last week I posted on the three methods to balance chemical equations.
0 Comments
4/2/2023 0 Comments Icedrive black friday 2021This is the last time this year you will get such crazy deals. I f you are looking for a cloud storage platform to backup your files, right now is the time to go for one. I have compiled a list of the best Black Friday deals in cloud storage that are so crazy good that it would be stupid for you to not take them. If your computer or smartphone malfunctions, you could lose all your work and personal files. Not backing up your files is a one-way ticket to disaster. And if you change your mind, you can revoke their access with just a click.īlack Friday officially starts on the Friday after Thanksgiving (on Friday, 24 November this year) and lasts through to Cyber Monday (on Monday, 27 November 2023). Want to send your wedding photos to your friends? Just click the share button and send them the link. The best part about storing your files on a cloud storage platform is the shareability. If you don’t want to lose years of your hard work or your precious family photos, it’s a great idea to backup your files on a cloud storage platform. Most people use Dropbox or Google Drive cloud storage to backup their personal and work files. It also allows you to share your files with other people such as clients and team members. Cloud storage is defined by IBM as a “service that allows you to save data and files in an off-site location that you access either through the public internet or a dedicated private network connection.”Ĭloud Storage is a way of storing your files on the internet that makes them accessible from anywhere in the world from any of your devices. Cloud storage is essentially a virtual hard drive for storing and sharing files online. 4/1/2023 0 Comments Rhino 7 fake![]() Companies benefitting from making synthetic / bio-fabricated horn have shown very little commitment to use their profits to help the core problem of rhino poaching besides which, those profits would meet only a tiny fraction of the total rhino protection costs that would remain to be met as long as demand reduction campaigns falter, as they would with the marketing of synthetic / bio-fabricated horn.How can consumers and law enforcement officials distinguish between legal synthetic / bio-fabricated horn that looks real, and illegal real horn?.It will take time to develop synthetic / bio-fabricated horn and meanwhile the poaching crisis continues.The availability of legal synthetic / bio-fabricated horn could normalise or remove the stigma from buying illegal real horn.Users buy from trusted sources and value “the real thing”.Synthetic / bio-fabricated horn could give credence to the notion that rhino horn has medicinal value, which is not supported by sound science.More than 90% of “rhino horns” in circulation are fake (mostly carved from buffalo horn or wood), but poaching rates continue to rise annually.There is no evidence that selling synthetic / bio-fabricated horn would reduce the demand for rhino horn or dispel the myths around rhino horn and could indeed lead to more poaching because it increases demand for “the real thing”.Having considered the available media coverage, SRI and IRF concluded that they were “opposed to the development, marketing and sale of synthetic rhino horn” for the following reasons: Will rhino poaching stop with the sale of synthetic / bio-fabricated rhino horn?.What is the impact on the synthetic / bio-fabricated horn business if trade in real rhino horn is legalised?.Will any proceeds from these synthetic / bio-fabricated rhino horns go towards rhino conservation?.How will synthetic / bio-fabricated horn be distinguished from real rhino horn?.How will synthetic / bio-fabricated rhino horn be priced?.Will people want to buy synthetic / bio-fabricated rhino horn?.How will this synthetic / bio-fabricated rhino horn be marketed and to whom?.How close will this synthetic / bio-fabricated rhino horn be to the real thing?.How are these companies proposing to manufacture synthetic / bio-fabricated horn?.In response to numerous media releases about the intent of several companies – Rhinoceros Horn LLC, Pembient and Stop Poaching Through Synthetic Rhino Horn – proposing to manufacture and sell synthetic / bio-fabricated rhino horn, in June 2015 SRI and IRF published a joint statement on their respective websites, which outlined the issues and claims:ĭrawing on interviews and articles published online, the statement asked a series of questions and expanded upon them: Save the Rhino International / International Rhino Foundation position Opposition to plans to produce synthetic / bio-fabricated rhino horn Those people or organizations working on demand-reduction and behaviour-change strategies in rhino horn consumer countries, who may be concerned that allowing trade in synthetic / bio-fabricated horn maintains and develops a consumer base that wishes to progress to real horn.Those people or organizations in favour of a legal international trade in rhino horn, who may be concerned about synthetic / bio-fabricated horn undercutting their potential marker.Law enforcement officials in rhino Range States, and rhino horn transit and consumer countries, who would be required to distinguish between illegal real rhino horn and potentially legal synthetic / bio-fabricated horn.The Nagoya Protocol has been adopted by 71 Parties (75 Ratifications ) (92 Signatures ) All international governments that must implement the Nagoya Protocol on Access to Genetic Resources and the Fair and Equitable Sharing of Benefits Arising from their Utilization (ABS) to the Convention on Biological Diversity, which provides a transparent legal framework for the effective implementation of one of the three objectives of the CBD: the fair and equitable sharing of benefits arising out of the utilization of genetic resources.The proposed development of synthetic / bio-fabricated rhino horn should concern a wide range of stakeholders: elephant ivory, lion bones or pangolin scales. Over the past two years or so, Save the Rhino International (SRI) and the International Rhino Foundation (IRF) have been monitoring the progress of four US-based companies that have announced their intentions – with varying degrees of success – to produce synthetic or bio-fabricated rhino horn, and occasionally also other products including e.g. ![]() Joint Statement by the International Rhino Foundation and Save the Rhino International. 4/1/2023 0 Comments Libressl base64 encoding![]() For this you could use base64.makeencoder. By default uses table with + as char for 62, / as char for 63 and as padding char. IMPLIED, INCLUDING BUT NOT LIMITED TO THE WARRANTIES OF MERCHANTABILITY,įITNESS FOR A PARTICULAR PURPOSE AND NONINFRINGEMENT. base64.encode ( str, encoder DEFAULT, usecache false ) Encodes str string using encoder table. THE SOFTWARE IS PROVIDED "AS IS", WITHOUT WARRANTY OF ANY KIND, EXPRESS OR The above copyright notice and this permission notice shall be included in allĬopies or substantial portions of the Software. To use, copy, modify, merge, publish, distribute, sublicense, and/or sellĬopies of the Software, and to permit persons to whom the Software isįurnished to do so, subject to the following conditions: Ive been trying to figure out the openssl documentation for base64 decoding and encoding. In the Software without restriction, including without limitation the rights Of this software and associated documentation files (the "Software"), to deal Permission is hereby granted, free of charge, to any person obtaining a copy it should work on any Posix compliant system e.g. I tried to run your code with a different base64 encoded key. Code presented here is both binary safe, and portable (i.e. Base64 encoding schemes are commonly used when there is a need to encode binary data that needs to be. The term Base64 originates from a specific MIME content transfer encoding. ![]() Herewith is an example of encoding to and from base64 using OpenSSL's C library. Base64 is a group of similar binary-to-text encoding schemes that represent binary data in an ASCII string format by translating it into a radix-64 representation. OpenSSL Base64 Encoding: Binary Safe and Portable ![]() In 1996, Fruit of the Loom bought the naming rights and named it "Pro Player" after its sports clothing line.ġ998, the year after the Marlins won the World Series, Huizenga dumped all of the team's talent saying he lost too much money and sold the team to John Henry. In 1994, Huizenga bought the rest of the stadium. He was granted the expansion Florida Marlins who started playing in 1993. The former video rental king, Blockbuster baron Wayne Huizenga, bought the DolphinsĪnd half of the stadium so he could pursue getting an expansion baseball team. Joe Robbie, whom this stadium was once named after, broke ground on the first all privatelyįinanced stadium for the National Football League (NFL) Miami Dolphins. Over again, I would buy the cheapest ticket and move to where I had the best view since the park is always empty anyway.ĭecemwas a sad day for many sports team owners. There was air conditioning and carpeting. Picture below, however it felt to fancy to be a baseball seat. These are the real expensive club seats that are sold for a football games but are reasonably priced for baseball. Where I Sat: I decided to splurge and go for Zone B Club Level. The nice thing about this stadium is that since no one comes to see the Marlins play, you can hear the players on the fieldĬalling each other off when they go for flys and the crack of the bat is a loud smack. If you could tear off the upper-deck it wouldĪctually be a not so bad baseball park. Remaining multi-team stadiums, that are all designed primarily for football, this one converts to baseball the best. The retired numbers lining the wall were all of Miami Dolphin players and the street the stadium is located on is Dan Marino Blvd. I didn't have high hopes for it since it is a multi-use stadium (the NFL Dolphins play here) and the focus was May 29, 2010, Roy Halladay (of the Phillies) pitches a perfect game.(of the Reds) gets career homerun number 600. September 10, 2000, Randy Johnson (of the Diamondbacks) gets career strikeout 3,000.Lower ticket prices.Opening Day: AugAp(baseball)Ĭost: $115 million, $10 million renovationsĪKA: Joe Robbie Stadium (1987-96), Pro Player Stadium (1997-2005), Dolphin(s) Stadium (2006-09), Land Shark Stadium (2009-10) For Baseball - Recommended For Kids and Family -įamily, mens and womens restrooms in 252 and 253.They are within five rows of the concourse (fewer stairs) and there is a men’s restroom, women’s restroom and concessions near this section. These seats were hand-selected for being close to a wide-range of amenities. ![]() ![]() For Baseball - Recommended For Outstanding Convenience.Do note however, that seeing plays deep in the outfield will be difficult from any row. Because they're already so far from the infield, the view won't be markedly different no matter which row you're in. That's no longer the case, but fans can still indulge on ballpark food from one of the two concession areas on this level. Mezzanine sections contain up to 17 rows of seats. While these seats are far away from home plate, this is a great place to hang out with a group and enjoy the game as a backdrop. Also known as the Chevy Mezzanine, these were once all-you-can-eat seats for Astros games. Mezzanine Seats at Minute Maid Park are the cheapest outfield seats for an Astros game. 4/1/2023 0 Comments Unpacking gamepass![]() You can read more about the games joining the service, along with new DLC and more, at the Xbox site. ![]() Minecraft: Java and Bedrock Editions – November 2Īs always, there's a spate of PC games leaving the service on November 15th.Here's the full list of PC release announced so far as coming in November: Unpacking 20 at Microsoft Store/ Free with Game Pass A place for everything Unloading boxes has never been this chill. ![]() How to unlock Fellowship Story-related, unlocks for completing the. Unpack accompanied by a soundtrack by BAFTA award-winning composer and audio director Jeff van Dyck. I've moved house roughly 12 times in 15 years, and yet I still like the look of satisfyingly placing books on shelves in this adorable indie game. Overview Unpacking Achievements Fellowship Achievement Fellowship Achievement in Unpacking Fellowship 10 Unpacked 2007. If you want to contribute please login or create an account. Unpacking, meanwhile, is about another constant in my life: moving home and unpacking boxes filled with all of your stuff. Unpacking - PCGamingWiki PCGW - bugs, fixes, crashes, mods, guides and improvements for every PC game Anonymous edits have been disabled on the wiki. It'll also arrive on Xbox Game Pass on its release date, November 9th. I don't love every iteration of the series - by which I mean, I don't become unhealthily obsessed with every iteration - but its continuation remains a comfort even if I am sick of its terrible press conferences. Unpacking is a game about the familiar experience of pulling possessions out of boxes and fitting them into a new home. Additionally, the low-fi music that both games have help lull players into that zen mode of arranging things based on if they feel right.Football Manager, meanwhile, is a series I've been returning to irregularly since I was 10-years-old. It does just what it says on the tin, and has you unpacking possessions to. A lot of fans play Minecraft specifically for the limitless design elements that it offers and Unpacking also gives players seemingly limitless options for how they'd like to design their homes' interiors. Unpacking Like Townscaper, Unpacking is another recent Xbox Game Pass addition which seems perfect for relaxing. Obviously, Minecraft can get a little stressful if fighting monsters, but when playing on Creative Mode, the two share a lot of qualities. Oddly enough, Minecraft and Unpacking share a zen-like quality that makes them both excellent titles for players to relax to. Open the Settings app it is the gear in the start menu. It launched today as an Xbox Game Pass Day One release for console, cloud, and PC. It's reminiscent of games like Animal Crossing: New Horizons where the focus is on aesthetic pleasure and deriving joy out of the smaller things in life. It's described as a zen game for players who are trying to relax and enjoy the simple pleasures of seeing all of their stuff as it gets individually unwrapped and hand-placed in whichever room it belongs in. Unpacking is a 'zen puzzle game' about moving into a new home, and the small stories our personal belongings tell. It does just what it says on the tin, and has you unpacking possessions to tidy. Unpacking is a brand new indie game that has players unpack boxes after a move and place their contents all over the different rooms in apartments and houses. Unpacking - Chloi Rads Most Anticipated Game Of 2020. Xbox Game Pass Unpacking is a zen game about the familiar experience of pulling possessions out of boxes and fitting them into a new home. Like Townscaper, Unpacking is another recent Xbox Game Pass addition which seems perfect for relaxing. RELATED: The Best New and Upcoming Games on Xbox Game Pass 4/1/2023 0 Comments Goodtask 3 tutorial![]() The program is synchronized on different types of devices and is available in different browsers.
4/1/2023 0 Comments Dota underlords knightsGathering a full stack of Elusive heroes isn’t exactly easy and somewhat of a risky strategy. The final tier of the bonus, in particular, is absolutely ridiculous. The Elusive Alliance grants your units a fantastic bonus that gives them a chance to evade incoming melee attacks. Global Item (Tier 1): Soul Sucking Syphon – Allied units 1 cell away from Warlocks heal for 25% of all damage caused by abilities and items. The Warlock Alliance struggles a bit in the early game but it more than makes up for it later on once you acquire AoE powerhouses like Alchemist, Disruptor, Necrophos, and Enigma. Once you get a full stack of these guys and have some of them at least at level 2, they’re absolutely devastating. The previous bonus was really great for supporting other Alliances but the current one seems better at keeping the warlocks themselves alive. Instead of healing at a constant rate like before, warlocks and their allies now heal huge chunks of damage at a time. Warlockĭespite the recent rework that changed the Alliance bonus, warlocks are still doing very well in Dota Underlords’ current meta. Global Item (Tier 2): Age of Chivalry: Non-Knight units gain +10% damage reduction for each alien Knight unit 1 cell away. Two of the knights are Human and one is a Demon, so you’ll also get a couple of nice additional bonuses for gathering the full stack. Five out of the six available knights are Tier 3 and below. Gathering at least four of them to unlock the second tier of the Alliance bonus is pretty easy. Gathering a full stack of six is definitely doable towards the late game. ![]() You only need two knights to start unlocking its powerful bonus and start building towards a strong defensive strategy. The Knight Alliance is undoubtedly one of the strongest ones in Dota Underlords right now. Global Item (Tier 3): Pocket Sand – Assassins blind enemies 1 cell away from where they land for 2 seconds (50% miss chance and 50% less mana when attacked) Knight Provided you also manage to level up some of your heroes of course. Getting the third one will make you nearly unstoppable. Getting the second tier bonus shouldn’t be too hard. The good news? There are nine assassins to choose from and they pop up constantly throughout all stages of the game. The bad news is that you’ll need to unlock at least the second tier of the Assassin bonus for these heroes to be truly effective and absolutely devastating in the late game. However, they also perform very well without extra help as this Alliance contains some of the strongest damage dealers in the game. Dota Underlords Tier List Ranked From S to D S Tier AssassinĪssassin heroes tend to be squishy so a common strategy is to pair them up with tankier characters. Alliances are ranked alphabetically within each tier. Other important factors include the number of heroes found in each alliance, their tier, how easy it is to acquire Alliance bonuses throughout the various stages of the game, and of course, the power of their bonuses. ![]() We’ve taken this into account when coming up with the ranks. Since every hero has at least two traits, you’ll inevitably start unlocking additional bonuses even if you only focus on gathering heroes from just a single Alliance. With that in mind, we’ve decided to rank all the Alliances in Dota Underlords based on their standalone effectiveness. Relying entirely on a single Alliance is often a risky strategy, but doing so can sometimes work in your favor. ![]() However, some are definitely better than others. All of these bonuses can be useful under the right circumstances. Heroes are grouped into Alliances and receive various bonuses when fighting alongside other characters that share the same traits. Dota Underlords is all about putting together a solid team composed of heroes that complement each other’s strengths and weaknesses. 4/1/2023 0 Comments Freedom writers book![]() ![]() ![]() Since April of last year, Brown has collaborated with the Freedom Writers Family to share her story. For the reader, the result is an intensely poignant experience of witnessing these young authors bare their truths to a mentor, friend, liberator, and in some ways, their future selves. Hand in hand, original Freedom Writers and Freedom Writer Teachers answer each letter with a message of compassion, understanding and profound advice as someone of similar plight, but who has come out on the other side. DEAR FREEDOM WRITER brings together different voices to share experiences of grief, pain, triumph, healing and solidarity, with each story so bravely written that it demands the reader’s attention. In these 50 letters and their corresponding replies, the Freedom Writers and Freedom Writer Teachers address issues that span generations and still impact young people today, such as struggles with abuse, racism, discrimination, poverty, incarceration, teen parenthood, mental health, self-harm, imposed borders, LGBTQIA+ identity and police violence. On their first day of high school, Erin Gruwells students had only three things in common: they hated school, they hated each other, and they hated her. In DEAR FREEDOM WRITER: Stories of Hardship and Hope from the Next Generation, their legacy continues as readers are introduced to a new league of Freedom Writers-50 students from around the globe-sharing deeply personal and powerful stories in letters addressed to the original Freedom Writers and dedicated Freedom Writer Teachers. Their stories, featured in the #1 New York Times bestseller THE FREEDOM WRITER’S DIARY, captured the hearts of readers everywhere and later became a major motion picture, FREEDOM WRITERS. What began in Room 203 in 1994 with a first-time teacher and 150 “unteachable” high schoolers, would go on to build a lifelong community of students and educators working together, driven by the purpose of innovative learning. More than 20 years ago, millions of readers were introduced to the Freedom Writers and teacher Erin Gruwell. Looking for books by Erin Gruwell See all books authored by Erin Gruwell, including The Freedom Writers Diary: How a Teacher and 150 Teens Used Writing to. LAPLACE - LaPlace native Jada Brown was among 50 students across the globe handpicked by Freedom Writer Teachers to lend a voice in the creation of the upcoming book, “DEAR FREEDOM WRITER: Stories of Hardship and Hope from the Next Generation.” 4/1/2023 0 Comments Mergepdf windowsIf you want the attachments to go before the email in reverse order, use -pdf multipage: prepend. If you want to create a single PDF from all emails contained in a folder, use the -pdf multipage:append switch:ĢPDF.exe -src "C:\Emails\*.*" -dst "C:\Out" -pdf multipage:appendĪs a result, you'll get an output "Combined.pdf" file containing your email and all attachments (if there were any). combine_prepend – join both email and its attachment to a single PDF (attachments before email)ĢPDF.exe -src "C:\Emails\*.*" -dst "C:\Out" -options attachments:ignore How to merge all emails with attachment(s) in a folder to one PDF.combine – join both email and its attachment to a single PDF (attachments after email). ![]()
|
AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |